| American Stainless & Alloy Products | 22 | 26 | 42,339.36 |
| American Stainless & Alloy Products. Inc. | 4 | 4 | 755.00 |
| Apac Carolina:Plant 691 Darlington | 1 | 1 | 1,639.80 |
| Chesterfield Lumber | 37 | 78 | 810,494.41 |
| Darlington County Landfill / Recycling | 28 | 28 | 4,171.29 |
| Darlington Shredding | 5 | 5 | 12,472.53 |
| Darlington Veneer | 6 | 13 | 31,300.72 |
| Galey&Lord:Society Hill | 35 | 274 | 6,261,273.79 |
| Hartsville Oil Mill | 33 | 115 | 785,812.55 |
| Nucor Steel:Darlington | 28 | 730 | 2,758,198.37 |
| Progress Energy Robinson Station | 81 | 420 | 28,529,841.65 |
| Royster-Clark Inc:Hartsville | 8 | 29 | 117,706.67 |
| Sonoco:Hartsville | 54 | 390 | 8,887,727.07 |
| Stingray Boats | 17 | 50 | 275,106.54 |
| Wellman Ind:Palmetto | 39 | 314 | 2,132,812.77 |